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SrTi(IO(3))(6)·2H(2)O and SrSn(IO(3))(6): distinct arrangements of lone pair electrons leading to large birefringences

Three new iodates SrTi(IO(3))(6)·2H(2)O, (H(3)O)(2)Ti(IO(3))(6), and SrSn(IO(3))(6) have been synthesized via a facile hydrothermal method. The three compounds have zero-dimensional crystal structures composed of one [MO(6)](8−) (M = Ti, Sn) octahedron connected with six [IO(3)](−) trigonal pyramids...

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Detalles Bibliográficos
Autores principales: Liu, Kaitong, Han, Jian, Huang, Junben, Wei, Zhonglei, Yang, Zhihua, Pan, Shilie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695646/
https://www.ncbi.nlm.nih.gov/pubmed/35423485
http://dx.doi.org/10.1039/d0ra10726c

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