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Synthesis of zirconocene complexes and their use in slurry-phase polymerisation of ethylene

A new family of zirconocene complexes of the type ((3-R)Ind(#))(2)ZrX(2) (where Ind(#) = C(6)Me(5)H and R = Me, Et and Ph) have been synthesised and fully characterised. Six new crystal structures have been reported (meso-((3-Et)Ind(#))(2)ZrBr(2), rac-((3-Et)Ind(#))(2)ZrCl(2), rac-((3-Et)Ind(#))(2)Z...

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Detalles Bibliográficos
Autores principales: Angpanitcharoen, Phakpoom, Lamb, Jessica V., Buffet, Jean-Charles, Turner, Zoë R., O'Hare, Dermot
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695961/
https://www.ncbi.nlm.nih.gov/pubmed/35423622
http://dx.doi.org/10.1039/d1ra01912k