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Unexpected ortho C–H bond activation in coordinated 7,8-benzoquinoline: synthesis and characterisation of heteroleptic Ir(iii)-7,8-benzoquinoline complexes
Two iridium(iii) complexes were isolated via the reaction of pyridine-2-aldoxime (Hpyrald) with 7,8-benzoquinoline (benzq)-derived iridium starting material, namely [(benzq)(2)Ir(μ-Cl)(2)Ir(benzq)(2)] (1). Among the two complexes, [Ir(III)(benzq)(2)(pyrald)] (2) and [Ir(III)(benzq-κN,κC(10))(benzq-κ...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697031/ https://www.ncbi.nlm.nih.gov/pubmed/35423828 http://dx.doi.org/10.1039/d1ra00860a |