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Photoinduced and ground state conversions in a cyclic β-thioxoketone
The photochemistry of a cyclic β-thioxoketone (2-methyl-1-(2-thioxycyclohexyl)propan-1-one (MTPO)) is investigated by NMR, UV, and IR experiments supported by DFT calculations. MTPO exists as a tautomeric mixture of an enol and a thiol form. Irradiation at low temperature led to a cis–trans isomeriz...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697321/ https://www.ncbi.nlm.nih.gov/pubmed/35425142 http://dx.doi.org/10.1039/d1ra09020h |