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Ring opening polymerization of d,l-lactide and ε-caprolactone catalysed by (pyrazol-1-yl)copper(ii) carboxylate complexes

1,2-Bis{(3,5-dimethylpyrazol-1-yl)methyl}benzene (L) reacts with [Cu(OAc)(2)] and C(6)H(5)COOH, 4-OH-C(6)H(4)COOH, 2-Cl-C(6)H(4)COOH and (3,5-NO(2))(2)-C(6)H(3)COOH to afford the copper complexes [Cu(2)(C(6)H(5)COO)(4)(L)(2)] (1), [Cu(2)(4-OH-C(6)H(4)COO)(4)(L)(2)] (2), [Cu(2)(2-Cl-C(6)H(4)COO)(4)(L...

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Detalles Bibliográficos
Autores principales: Appavoo, Divambal, Spencer, Lara C., Guzei, Ilia A., Gómez-García, Carlos J., van Wyk, Juanita L., Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697578/
https://www.ncbi.nlm.nih.gov/pubmed/35423870
http://dx.doi.org/10.1039/d1ra00339a