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Crown Ether-Derived Chiral BINOL: Enantioselective Michael Addition of Alkenyl Boronic Acids to α,β-Unsaturated Ketones

[Image: see text] A new class of aza-crown ether-derived chiral BINOL catalysts were designed, synthesized, and applied in the asymmetric Michael addition of alkenylboronic acids to α,β-unsaturated ketones. It was found that introducing aza-crown ethers to the BINOL catalyst could achieve apparently...

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Detalles Bibliográficos
Autores principales: Tao, Jia-Ju, Tang, Jia-Dong, Hong, Tao, Ye, Jia-Wen, Chen, Jia-Yu, Xie, Chunsong, Zhang, Zibin, Li, Shijun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697596/
https://www.ncbi.nlm.nih.gov/pubmed/34963990
http://dx.doi.org/10.1021/acsomega.1c05875