A new donor for charge-transfer systems: synthesis and properties of 2,4,7,9-tetramethyl-1,6-dithiapyrene (TMDTP) and structure of (TMDTP)(3)(PF(6))(2)·2THF and TMDTP–TCNQ

The heterocyclic donor molecule 2,4,7,9-tetramethyl-1,6-dithiapyrene (TMDTP) has been synthesized in five steps. Oxidation of TMDTP is facile (E(1)(1/2) = 0.27 V and E(2)(1/2) = 0.79 V vs. SCE). The charge-transfer complex, TMDTP–TCNQ, has been prepared and the salt, (TMDTP)(3)(PF(6))(2)·2THF, obtai...

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Detalles Bibliográficos
Autores principales: Bendix, Jesper, Bechgaard, Klaus, Christensen, Jørn Bolstad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697854/
https://www.ncbi.nlm.nih.gov/pubmed/35423969
http://dx.doi.org/10.1039/d1ra00587a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8697854/
https://www.ncbi.nlm.nih.gov/pubmed/35423969
http://dx.doi.org/10.1039/d1ra00587a

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