DABCO-promoted photocatalytic C–H functionalization of aldehydes

Herein we present a direct application of DABCO, an inexpensive and broadly accessible organic base, as a hydrogen atom transfer (HAT) abstractor in a photocatalytic strategy for aldehyde C–H activation. The acyl radicals generated in this step were arylated with aryl bromides through a well stablis...

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Detalles Bibliográficos
Autores principales: Maia da Silva Santos, Bruno, dos Santos Dupim, Mariana, Paula de Souza, Cauê, Messias Cardozo, Thiago, Gadini Finelli, Fernanda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8712972/
https://www.ncbi.nlm.nih.gov/pubmed/35003372
http://dx.doi.org/10.3762/bjoc.17.205

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8712972/
https://www.ncbi.nlm.nih.gov/pubmed/35003372
http://dx.doi.org/10.3762/bjoc.17.205

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