Molecular Approach to Alkali-Metal Encapsulation by a Prussian Blue Analogue Fe(II)/Co(III) Cube in Aqueous Solution: A Kineticomechanistic Exchange Study

[Image: see text] The preparation of a series of alkali-metal inclusion complexes of the molecular cube [{Co(III)(Me(3)-tacn)}(4){Fe(II)(CN)(6)}(4)](4–) (Me(3)-tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane), a mixed-valent Prussian Blue analogue bearing bridging cyanido ligands, has been achieved b...

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Detalles Bibliográficos
Autores principales: Gonzálvez, Miguel A., Bernhardt, Paul V., Font-Bardia, Mercè, Gallen, Albert, Jover, Jesús, Ferrer, Montserrat, Martínez, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8715505/
https://www.ncbi.nlm.nih.gov/pubmed/34766767
http://dx.doi.org/10.1021/acs.inorgchem.1c03001

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8715505/
https://www.ncbi.nlm.nih.gov/pubmed/34766767
http://dx.doi.org/10.1021/acs.inorgchem.1c03001

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