Combined Theoretical and Experimental Studies Unravel Multiple Pathways to Convergent Asymmetric Hydrogenation of Enamides

[Image: see text] We present a highly efficient convergent asymmetric hydrogenation of E/Z mixtures of enamides catalyzed by N,P–iridium complexes supported by mechanistic studies. It was found that reduction of the olefinic isomers (E and Z geometries) produces chiral amides with the same absolute...

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Detalles Bibliográficos
Autores principales: Yang, Jianping, Massaro, Luca, Krajangsri, Suppachai, Singh, Thishana, Su, Hao, Silvi, Emanuele, Ponra, Sudipta, Eriksson, Lars, Ahlquist, Mårten S. G., Andersson, Pher G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8719336/
https://www.ncbi.nlm.nih.gov/pubmed/34905345
http://dx.doi.org/10.1021/jacs.1c09573

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8719336/
https://www.ncbi.nlm.nih.gov/pubmed/34905345
http://dx.doi.org/10.1021/jacs.1c09573

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