Ga(+)-catalyzed hydrosilylation? About the surprising system Ga(+)/HSiR(3)/olefin, proof of oxidation with subvalent Ga(+) and silylium catalysis with perfluoroalkoxyaluminate anions

Already 1 mol% of subvalent [Ga(PhF)(2)](+)[pf](−) ([pf](−) = [Al(OR(F))(4)](−), R(F) = C(CF(3))(3)) initiates the hydrosilylation of olefinic double bonds under mild conditions. Reactions with HSiMe(3) and HSiEt(3) as substrates efficiently yield anti-Markovnikov and anti-addition products, while b...

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Detalles Bibliográficos
Autores principales: Barthélemy, Antoine, Glootz, Kim, Scherer, Harald, Hanske, Annaleah, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8729802/
https://www.ncbi.nlm.nih.gov/pubmed/35126976
http://dx.doi.org/10.1039/d1sc05331k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8729802/
https://www.ncbi.nlm.nih.gov/pubmed/35126976
http://dx.doi.org/10.1039/d1sc05331k

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