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Ga(+)-catalyzed hydrosilylation? About the surprising system Ga(+)/HSiR(3)/olefin, proof of oxidation with subvalent Ga(+) and silylium catalysis with perfluoroalkoxyaluminate anions
Already 1 mol% of subvalent [Ga(PhF)(2)](+)[pf](−) ([pf](−) = [Al(OR(F))(4)](−), R(F) = C(CF(3))(3)) initiates the hydrosilylation of olefinic double bonds under mild conditions. Reactions with HSiMe(3) and HSiEt(3) as substrates efficiently yield anti-Markovnikov and anti-addition products, while b...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8729802/ https://www.ncbi.nlm.nih.gov/pubmed/35126976 http://dx.doi.org/10.1039/d1sc05331k |