Cargando…
Hypervalent iodine promoted the synthesis of cycloheptatrienes and cyclopropanes
A new strategy is reported for intramolecular Buchner-type reactions using PIDA as a promotor. Traditionally, the Buchner reaction is achieved via Rh-carbenoids derived from Rh(II) catalysts with diazo compounds. Herein, the first metal-free Buchner-type reaction to construct highly strained cyclohe...
Autores principales: | , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8729816/ https://www.ncbi.nlm.nih.gov/pubmed/35126980 http://dx.doi.org/10.1039/d1sc05429e |