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Hypervalent iodine promoted the synthesis of cycloheptatrienes and cyclopropanes

A new strategy is reported for intramolecular Buchner-type reactions using PIDA as a promotor. Traditionally, the Buchner reaction is achieved via Rh-carbenoids derived from Rh(II) catalysts with diazo compounds. Herein, the first metal-free Buchner-type reaction to construct highly strained cyclohe...

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Detalles Bibliográficos
Autores principales: Yuan, Da-Fu, Wang, Zi-Chen, Geng, Rui-Sen, Ren, Guang-Yi, Wright, James S., Ni, Shao-Fei, Li, Ming, Wen, Li-Rong, Zhang, Lin-Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8729816/
https://www.ncbi.nlm.nih.gov/pubmed/35126980
http://dx.doi.org/10.1039/d1sc05429e