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Hypervalent iodine promoted the synthesis of cycloheptatrienes and cyclopropanes
A new strategy is reported for intramolecular Buchner-type reactions using PIDA as a promotor. Traditionally, the Buchner reaction is achieved via Rh-carbenoids derived from Rh(II) catalysts with diazo compounds. Herein, the first metal-free Buchner-type reaction to construct highly strained cyclohe...
Autores principales: | Yuan, Da-Fu, Wang, Zi-Chen, Geng, Rui-Sen, Ren, Guang-Yi, Wright, James S., Ni, Shao-Fei, Li, Ming, Wen, Li-Rong, Zhang, Lin-Bao |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8729816/ https://www.ncbi.nlm.nih.gov/pubmed/35126980 http://dx.doi.org/10.1039/d1sc05429e |
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