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Opportunities and challenges of applying advanced X-ray spectroscopy to actinide and lanthanide N-donor ligand systems

N-donor ligands such as n-Pr-BTP [2,6-bis­(5,6-di­propyl-1,2,4-triazin-3-yl)­pyridine] preferentially bind trivalent actinides (An(3+)) over trivalent lanthanides (Ln(3+)) in liquid–liquid separation. However, the chemical and physical processes responsible for this selectivity are not yet well unde...

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Detalles Bibliográficos
Autores principales: Pruessmann, Tim, Nagel, Peter, Simonelli, Laura, Batchelor, David, Gordon, Robert, Schimmelpfennig, Bernd, Trumm, Michael, Vitova, Tonya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8733980/
https://www.ncbi.nlm.nih.gov/pubmed/34985423
http://dx.doi.org/10.1107/S1600577521012091