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Enzymatic Bromocyclization of α‐ and γ‐Allenols by Chloroperoxidase from Curvularia inaequalis

Vanadate‐dependent chloroperoxidase from Curvularia inaequalis catalyzes 5‐endo‐trig bromocyclizations of α‐allenols to produce valuable halofunctionalized furans as versatile synthetic building blocks. In contrast to other haloperoxidases, also the more challenging 5‐exo‐trig halocyclizations of γ‐...

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Detalles Bibliográficos
Autores principales: Naapuri, Janne M., Wagner, Philip K., Hollmann, Frank, Deska, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8734111/
https://www.ncbi.nlm.nih.gov/pubmed/34981903
http://dx.doi.org/10.1002/open.202100236