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Efficient Syntheses of Biobased Terephthalic Acid, p-Toluic Acid, and p-Methylacetophenone via One-Pot Catalytic Aerobic Oxidation of Monoterpene Derived Bio-p-cymene
[Image: see text] An efficient elevated-pressure catalytic oxidative process (2.5 mol % Co(NO(3))(2), 2.5 mol % MnBr(2), air (30 bar), 125 °C, acetic acid, 6 h) has been developed to oxidize p-cymene into crystalline white terephthalic acid (TA) in ∼70% yield. Use of this mixed Co(2+)/Mn(2+) catalyt...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8735764/ https://www.ncbi.nlm.nih.gov/pubmed/35024250 http://dx.doi.org/10.1021/acssuschemeng.1c02605 |