Cargando…
Efficient Syntheses of Biobased Terephthalic Acid, p-Toluic Acid, and p-Methylacetophenone via One-Pot Catalytic Aerobic Oxidation of Monoterpene Derived Bio-p-cymene
[Image: see text] An efficient elevated-pressure catalytic oxidative process (2.5 mol % Co(NO(3))(2), 2.5 mol % MnBr(2), air (30 bar), 125 °C, acetic acid, 6 h) has been developed to oxidize p-cymene into crystalline white terephthalic acid (TA) in ∼70% yield. Use of this mixed Co(2+)/Mn(2+) catalyt...
Autores principales: | Tibbetts, Joshua D., Russo, Danilo, Lapkin, Alexei A., Bull, Steven D. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8735764/ https://www.ncbi.nlm.nih.gov/pubmed/35024250 http://dx.doi.org/10.1021/acssuschemeng.1c02605 |
Ejemplares similares
-
Update on Monoterpenes as Antimicrobial Agents: A Particular Focus on p-Cymene
por: Marchese, Anna, et al.
Publicado: (2017) -
Antinociceptive Activity and Redox Profile of the Monoterpenes (+)-Camphene, p-Cymene, and Geranyl Acetate in Experimental Models
por: Quintans-Júnior, Lucindo, et al.
Publicado: (2013) -
Computational Investigations of a pH-Induced Structural Transition in a CTAB Solution with Toluic Acid
por: Wang, Tingyi, et al.
Publicado: (2021) -
Synthesis and Verification of Biobased Terephthalic Acid from Furfural
por: Tachibana, Yuya, et al.
Publicado: (2015) -
Synthesis of Biotin Linkers with the Activated Triple Bond Donor [p-(N-propynoylamino)toluic Acid] (PATA) for Efficient Biotinylation of Peptides and Oligonucleotides
por: Jezowska, Martina, et al.
Publicado: (2012)