SOMOphilic Alkynylation of Unreactive Alkenes Enabled by Iron-Catalyzed Hydrogen Atom Transfer

We report an efficient and practical iron-catalyzed hydrogen atom transfer protocol for assembling acetylenic motifs into functional alkenes. Diversities of internal alkynes could be obtained from readily available alkenes and acetylenic sulfones with excellent Markovnikov selectivity. An iron hydri...

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Detalles Bibliográficos
Autores principales: Zhao, Binlin, Zhu, Tianxiang, Ma, Mengtao, Shi, Zhuangzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746543/
https://www.ncbi.nlm.nih.gov/pubmed/35011265
http://dx.doi.org/10.3390/molecules27010033

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746543/
https://www.ncbi.nlm.nih.gov/pubmed/35011265
http://dx.doi.org/10.3390/molecules27010033

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