Preparation of Oxysterols by C–H Oxidation of Dibromocholestane with Ru(Bpga) Catalyst

Seven mono- and dihydroxycholesterols were prepared by direct C–H oxidation of the cholestane skeleton with a recently developed Ru(Bpga) catalyst (Ru(Bpga) = [RuCl (bpga) (PPh(3))] Cl; bpga = 2-(bis(pyridin-2-ylmethyl)amino)-N-(2,6-dimethylphenyl)acetamide)). Due to the high selectivity of the Ru(B...

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Detalles Bibliográficos
Autores principales: Fujii, Yui, Yoritate, Makoto, Makino, Kana, Igawa, Kazunobu, Takeda, Daiki, Doiuchi, Daiki, Tomooka, Katsuhiko, Uchida, Tatsuya, Hirai, Go
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746986/
https://www.ncbi.nlm.nih.gov/pubmed/35011456
http://dx.doi.org/10.3390/molecules27010225

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746986/
https://www.ncbi.nlm.nih.gov/pubmed/35011456
http://dx.doi.org/10.3390/molecules27010225

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