Absence of Intermediates in the BINOL-Derived Mg(II)/Phosphate-Catalyzed Desymmetrizative Ring Expansion of 1-Vinylcyclobutanols

[Image: see text] The catalyzed desymmetrizative ring expansion of alkenylcyclobutanols promoted by halofunctionalization of the alkene moiety with N-bromosuccinimide has been experimentally and computationally studied. The reaction yields highly enantioenriched cyclopentanones bearing two all-carbo...

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Detalles Bibliográficos
Autores principales: Capel, Estefania, Rodríguez-Rodríguez, Marta, Uria, Uxue, Pedron, Manuel, Tejero, Tomas, Vicario, Jose L., Merino, Pedro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8749959/
https://www.ncbi.nlm.nih.gov/pubmed/34928602
http://dx.doi.org/10.1021/acs.joc.1c02699

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8749959/
https://www.ncbi.nlm.nih.gov/pubmed/34928602
http://dx.doi.org/10.1021/acs.joc.1c02699

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