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Magneto-structural Correlations in Ni(2+)–Halide···Halide–Ni(2+) Chains
[Image: see text] We present the magnetic properties of a new family of S = 1 molecule-based magnets, NiF(2)(3,5-lut)(4)·2H(2)O and NiX(2)(3,5-lut)(4), where X = HF(2), Cl, Br, or I (lut = lutidine C(7)H(9)N). Upon creation of isolated Ni–X···X–Ni and Ni–F–H–F···F–H–F–Ni chains separated by bulky an...
Autores principales: | , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8753652/ https://www.ncbi.nlm.nih.gov/pubmed/34939800 http://dx.doi.org/10.1021/acs.inorgchem.1c02483 |