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Magneto-structural Correlations in Ni(2+)–Halide···Halide–Ni(2+) Chains

[Image: see text] We present the magnetic properties of a new family of S = 1 molecule-based magnets, NiF(2)(3,5-lut)(4)·2H(2)O and NiX(2)(3,5-lut)(4), where X = HF(2), Cl, Br, or I (lut = lutidine C(7)H(9)N). Upon creation of isolated Ni–X···X–Ni and Ni–F–H–F···F–H–F–Ni chains separated by bulky an...

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Detalles Bibliográficos
Autores principales: Blackmore, William J. A., Curley, Samuel P. M., Williams, Robert C., Vaidya, Shroya, Singleton, John, Birnbaum, Serena, Ozarowski, Andrew, Schlueter, John A., Chen, Yu-Sheng, Gillon, Beatrice, Goukassov, Arsen, Kibalin, Iurii, Villa, Danielle Y., Villa, Jacqueline A., Manson, Jamie L., Goddard, Paul A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8753652/
https://www.ncbi.nlm.nih.gov/pubmed/34939800
http://dx.doi.org/10.1021/acs.inorgchem.1c02483