Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Thietane 1,1-Dioxides

[Image: see text] A palladium-catalyzed decarboxylative asymmetric allylic alkylation of thietane 1,1-dioxides via linear enolate intermediates from racemic starting materials has been developed. This process installs an α-sulfonyl tetrasubstituted stereogenic center with high enantioselectivity. Th...

Descripción completa

Detalles Bibliográficos
Autores principales: Laidlaw, Gillian, Franckevičius, Vilius
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8762707/
https://www.ncbi.nlm.nih.gov/pubmed/34914384
http://dx.doi.org/10.1021/acs.orglett.1c04075

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8762707/
https://www.ncbi.nlm.nih.gov/pubmed/34914384
http://dx.doi.org/10.1021/acs.orglett.1c04075

Ejemplares similares