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Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Thietane 1,1-Dioxides
[Image: see text] A palladium-catalyzed decarboxylative asymmetric allylic alkylation of thietane 1,1-dioxides via linear enolate intermediates from racemic starting materials has been developed. This process installs an α-sulfonyl tetrasubstituted stereogenic center with high enantioselectivity. Th...
Autores principales: | Laidlaw, Gillian, Franckevičius, Vilius |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8762707/ https://www.ncbi.nlm.nih.gov/pubmed/34914384 http://dx.doi.org/10.1021/acs.orglett.1c04075 |
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