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Photocatalytic defluoroalkylation and hydrodefluorination of trifluoromethyls using o-phosphinophenolate
Under visible light irradiation, o-phosphinophenolate functions as an easily accessible photoredox catalyst to activate trifluoromethyl groups in trifluoroacetamides, trifluoroacetates, and trifluoromethyl (hetero)arenes to deliver corresponding difluoromethyl radicals. It works in relay with a thio...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8764036/ https://www.ncbi.nlm.nih.gov/pubmed/35039496 http://dx.doi.org/10.1038/s41467-022-28007-2 |