Computational Investigation on the Origin of Atroposelectivity for the Cinchona Alkaloid Primary Amine-Catalyzed Vinylogous Desymmetrization of N-(2-t-Butylphenyl)maleimides

[Image: see text] Mechanistic studies clarifying how chiral primary amines control the stereochemistry of vinylogous processes are rare. We report a density functional theory (DFT) computational study for the comprehension of the reaction mechanism of the vinylogous atroposelective desymmetrization...

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Detalles Bibliográficos
Autores principales: Tampellini, Nicolò, Righi, Paolo, Bencivenni, Giorgio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8764656/
https://www.ncbi.nlm.nih.gov/pubmed/34347451
http://dx.doi.org/10.1021/acs.joc.1c01235

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8764656/
https://www.ncbi.nlm.nih.gov/pubmed/34347451
http://dx.doi.org/10.1021/acs.joc.1c01235

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