Borane-catalyzed cascade Friedel–Crafts alkylation/[1,5]-hydride transfer/Mannich cyclization to afford tetrahydroquinolines

An unprecedented redox-neutral annulation reaction of tertiary anilines with electron-deficient alkynes was developed that proceeds through a cascade Friedel–Crafts alkylation/[1,5]-hydride transfer/Mannich cyclization sequence. Under B(C(6)F(5))(3) catalysis, a range of functionalized 1,2,3,4-tetra...

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Detalles Bibliográficos
Autores principales: Zhang, Bei-Bei, Peng, Shuo, Wang, Feiyi, Lu, Cuifen, Nie, Junqi, Chen, Zuxing, Yang, Guichun, Ma, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8768868/
https://www.ncbi.nlm.nih.gov/pubmed/35173942
http://dx.doi.org/10.1039/d1sc05629h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8768868/
https://www.ncbi.nlm.nih.gov/pubmed/35173942
http://dx.doi.org/10.1039/d1sc05629h

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