Cargando…

Borane-catalyzed cascade Friedel–Crafts alkylation/[1,5]-hydride transfer/Mannich cyclization to afford tetrahydroquinolines

An unprecedented redox-neutral annulation reaction of tertiary anilines with electron-deficient alkynes was developed that proceeds through a cascade Friedel–Crafts alkylation/[1,5]-hydride transfer/Mannich cyclization sequence. Under B(C(6)F(5))(3) catalysis, a range of functionalized 1,2,3,4-tetra...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zhang, Bei-Bei, Peng, Shuo, Wang, Feiyi, Lu, Cuifen, Nie, Junqi, Chen, Zuxing, Yang, Guichun, Ma, Chao
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8768868/ https://www.ncbi.nlm.nih.gov/pubmed/35173942 http://dx.doi.org/10.1039/d1sc05629h

Ejemplares similares

Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction
por: Dong, Yafang, et al.
Publicado: (2020)

Lewis Acid-Catalyzed Enantioselective Friedel–Crafts Alkylation of Pyrrole in Water
por: Sun, Jianan, et al.
Publicado: (2020)

Asymmetric Friedel-Crafts Alkylation of Indole with Chalcones Catalyzed by Chiral Phosphoric Acids
por: Scettri, Arrigo, et al.
Publicado: (2009)

Friedel–Crafts alkylation reaction with fluorinated alcohols as hydrogen-bond donors and solvents
por: Tang, Ren-Jin, et al.
Publicado: (2018)

Tandem Friedel‐Crafts‐Alkylation‐Enantioselective‐Protonation by Artificial Enzyme Iminium Catalysis
por: Leveson‐Gower, Reuben B., et al.
Publicado: (2022)

Mechanochemical Friedel–Crafts acylations
por: Đud, Mateja, et al.
Publicado: (2019)

Biocatalytic Friedel‐Crafts Reactions
por: Leveson‐Gower, Reuben B., et al.
Publicado: (2022)

Multivalent polyglycerol supported imidazolidin-4-one organocatalysts for enantioselective Friedel–Crafts alkylations
por: Pecchioli, Tommaso, et al.
Publicado: (2015)

Friedel–Crafts Alkylation over Zr-Mont Catalyst for the Production of Diesel Fuel Precursors
por: Shinde, Suhas H., et al.
Publicado: (2018)

Diastereoselective ring opening of fully-substituted cyclopropanes via intramolecular Friedel–Crafts alkylation
por: Lanke, Veeranjaneyulu, et al.
Publicado: (2019)

Friedel–Crafts acylation of benzene derivatives in tunable aryl alkyl ionic liquids (TAAILs)
por: Lerch, Swantje, et al.
Publicado: (2023)

One-Pot Synthesis of Polynuclear Indole Derivatives by Friedel–Crafts Alkylation of γ-Hydroxybutyrolactams
por: Abaev, Vladimir T., et al.
Publicado: (2023)

A review of new developments in the Friedel–Crafts alkylation – From green chemistry to asymmetric catalysis
por: Rueping, Magnus, et al.
Publicado: (2010)

Hafnium-Doped Mesoporous Silica as Efficient Lewis Acidic Catalyst for Friedel–Crafts Alkylation Reactions
por: Huang, Yao-Bing, et al.
Publicado: (2019)

Rose bengal as photocatalyst: visible light-mediated Friedel–Crafts alkylation of indoles with nitroalkenes in water
por: Yu, Zong-Yi, et al.
Publicado: (2020)

Catalytic asymmetric tandem Friedel–Crafts alkylation/Michael addition reaction for the synthesis of highly functionalized chromans
por: Peng, Jiahuan, et al.
Publicado: (2013)

Artificial Metalloenzymes based on TetR Proteins and Cu(II) for Enantioselective Friedel‐Crafts Alkylation Reactions
por: Gutiérrez de Souza, Cora, et al.
Publicado: (2020)

Biocatalytic Friedel–Crafts Acylation and Fries Reaction
por: Schmidt, Nina G., et al.
Publicado: (2017)

Friedel–Crafts Type Methylation with Dimethylhalonium Salts
por: Hämmerling, Sebastian, et al.
Publicado: (2020)

The hetero-Friedel-Crafts-Bradsher Cyclizations with Formation of Ring Carbon-Heteroatom (P, S) Bonds, Leading to Organic Functional Materials
por: Skalik, Joanna, et al.
Publicado: (2020)

Asymmetric one-pot sequential Friedel–Crafts-type alkylation and α-oxyamination catalyzed by a peptide and an enzyme
por: Akagawa, Kengo, et al.
Publicado: (2012)

Development of highly efficient Friedel–Crafts alkylations with alcohols using heterogeneous catalysts under continuous-flow conditions
por: Masuda, Koichiro, et al.
Publicado: (2021)

O,S-Acetals in a New Modification of oxo-Friedel–Crafts–Bradsher Cyclization—Synthesis of Fluorescent (Hetero)acenes and Mechanistic Considerations
por: Owsianik, Krzysztof, et al.
Publicado: (2023)

Asymmetric Catalytic Friedel–Crafts Reactions of Unactivated Arenes
por: Brunen, Sebastian, et al.
Publicado: (2023)

Cascade intramolecular Prins/Friedel–Crafts cyclization for the synthesis of 4-aryltetralin-2-ols and 5-aryltetrahydro-5H-benzo[7]annulen-7-ols
por: Zheng, Jie, et al.
Publicado: (2021)

Iridium-Catalyzed Reductive Nitro-Mannich Cyclization
por: Gregory, Alex W, et al.
Publicado: (2015)

Enantio- and diastereoselective conjugate borylation/Mannich cyclization
por: Larin, Egor M., et al.
Publicado: (2020)

Structure and Catalytic Mechanism of a Bacterial Friedel–Crafts Acylase
por: Pavkov‐Keller, Tea, et al.
Publicado: (2018)

Applications of Friedel–Crafts reactions in total synthesis of natural products
por: Heravi, Majid M., et al.
Publicado: (2018)

Recent Advances in the Catalytic Asymmetric Friedel–Crafts Reactions of Indoles
por: Ahmad, Tauqir, et al.
Publicado: (2022)

A rational quest for selectivity through precise ligand-positioning in tandem DNA-catalysed Friedel–Crafts alkylation/asymmetric protonation
por: Mansot, Justine, et al.
Publicado: (2019)

Exploiting the Chiral Ligands of Bis(imidazolinyl)- and Bis(oxazolinyl)thiophenes—Synthesis and Application in Cu-Catalyzed Friedel–Crafts Asymmetric Alkylation
por: Islam, Mohammad Shahidul, et al.
Publicado: (2021)

[1,5]-Hydride Shift Triggered N-Dealkylative Cyclization into 2-Oxo-1,2,3,4-tetrahydroquinoline-3-carboxylates via Boronate Complexes
por: Zaitseva, Elvira R., et al.
Publicado: (2022)

AlCl(3)·6H(2)O-Catalyzed Friedel-Crafts Alkylation of Indoles by the para-Quinone Methide Moiety of Celastrol
por: Zhu, Yi, et al.
Publicado: (2017)

Functionalizing Polystyrene with N-Alicyclic Piperidine-Based Cations via Friedel–Crafts Alkylation for Highly Alkali-Stable Anion-Exchange Membranes
por: Olsson, Joel S., et al.
Publicado: (2020)

Catalytic asymmetric Friedel–Crafts alkylation of unprotected indoles with nitroalkenes using a novel chiral Yb(OTf)(3)–pybox complex
por: Karimi, Babak, et al.
Publicado: (2023)

Mechanism of Biocatalytic Friedel–Crafts Acylation by Acyltransferase from Pseudomonas protegens
por: Sheng, Xiang, et al.
Publicado: (2019)

Generation and Reactivity of 1-Imidocarbenium Cations in the Friedel–Crafts-type Reaction
por: Adamek, Jakub, et al.
Publicado: (2022)

Synthesis of Seco-Chlorinated Derivatives of Phenanthroindolizidine Precursors via Friedel-Crafts Reaction
por: Li, Songtao, et al.
Publicado: (2010)

Friedel–Crafts approach to the one-pot synthesis of methoxy-substituted thioxanthylium salts
por: Tanaka, Kenta, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_h3uhg6hedhagtitp63qlr5328d