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Electrochemical and Mechanistic Study of Reactivities of α-, β-, γ-, and δ-Tocopherol toward Electrogenerated Superoxide in N,N-Dimethylformamide through Proton-Coupled Electron Transfer

Scavenging of superoxide radical anion (O(2)(•−)) by tocopherols (TOH) and related compounds was investigated on the basis of cyclic voltammetry and in situ electrolytic electron spin resonance spectrum in N,N-dimethylformamide (DMF) with the aid of density functional theory (DFT) calculations. Quas...

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Detalles Bibliográficos
Autores principales: Nakayama, Tatsushi, Honda, Ryo, Kuwata, Kazuo, Usui, Shigeyuki, Uno, Bunji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8773314/
https://www.ncbi.nlm.nih.gov/pubmed/35052513
http://dx.doi.org/10.3390/antiox11010009