Stereoselective hydrogen atom transfer to acyclic radicals: a switch enabling diastereodivergent borylative radical cascades

Radical cascade reactions are powerful tools to construct structurally complex molecules. However, the stereochemical control of acyclic radical intermediates remains a persistent challenge, due to the low differentiation between the two faces of these species. This hurdle further makes stereodiverg...

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Detalles Bibliográficos
Autores principales: Ye, Tian, Zhang, Feng-Lian, Xia, Hui-Min, Zhou, Xi, Yu, Zhi-Xiang, Wang, Yi-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8776760/
https://www.ncbi.nlm.nih.gov/pubmed/35058459
http://dx.doi.org/10.1038/s41467-022-28071-8

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8776760/
https://www.ncbi.nlm.nih.gov/pubmed/35058459
http://dx.doi.org/10.1038/s41467-022-28071-8

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