Ag(2)O versus Cu(2)O in the Catalytic Isomerization of Coordinated Diaminocarbenes to Formamidines: A Theoretical Study

DFT theoretical calculations for the Ag(2)O-induced isomerization process of diaminocarbenes to formamidines, coordinated to Mn(I), have been carried out. The reaction mechanism found involves metalation of an N-H residue of the carbene ligand by the catalyst Ag(2)O and the formation of a key transi...

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Detalles Bibliográficos
Autores principales: Van der Maelen, Juan F., Ruiz, Javier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8778719/
https://www.ncbi.nlm.nih.gov/pubmed/35057208
http://dx.doi.org/10.3390/ma15020491

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8778719/
https://www.ncbi.nlm.nih.gov/pubmed/35057208
http://dx.doi.org/10.3390/ma15020491

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