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Ag(2)O versus Cu(2)O in the Catalytic Isomerization of Coordinated Diaminocarbenes to Formamidines: A Theoretical Study
DFT theoretical calculations for the Ag(2)O-induced isomerization process of diaminocarbenes to formamidines, coordinated to Mn(I), have been carried out. The reaction mechanism found involves metalation of an N-H residue of the carbene ligand by the catalyst Ag(2)O and the formation of a key transi...
Autores principales: | Van der Maelen, Juan F., Ruiz, Javier |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8778719/ https://www.ncbi.nlm.nih.gov/pubmed/35057208 http://dx.doi.org/10.3390/ma15020491 |
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