Cargando…

Alkylation of Nitropyridines via Vicarious Nucleophilic Substitution

[Image: see text] Electrophilic nitropyridines react with sulfonyl-stabilized carbanions to give products of C–H alkylation via vicarious nucleophilic substitution. The process consists of formation of the Meisenheimer-type adduct followed by base-induced β-elimination of the sulfinic acid (e.g., Ph...

Descripción completa

Detalles Bibliográficos
Autores principales: Antoniak, Damian, Barbasiewicz, Michał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8787753/
https://www.ncbi.nlm.nih.gov/pubmed/34978826
http://dx.doi.org/10.1021/acs.orglett.1c03920