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Alkylation of Nitropyridines via Vicarious Nucleophilic Substitution
[Image: see text] Electrophilic nitropyridines react with sulfonyl-stabilized carbanions to give products of C–H alkylation via vicarious nucleophilic substitution. The process consists of formation of the Meisenheimer-type adduct followed by base-induced β-elimination of the sulfinic acid (e.g., Ph...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8787753/ https://www.ncbi.nlm.nih.gov/pubmed/34978826 http://dx.doi.org/10.1021/acs.orglett.1c03920 |