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The reaction of rhenium nitrosyl with a sterically hindered NHC-carbene
In this article, we present the serendipitous synthesis of the unknown Re(i) complex [(OPPh(3))Re(NO)(2)Cl(3)] (3) that we obtained reacting the Re(v) complex trans-[(PPh(3))(2)ReOCl(3)] (1) with NO gas in presence of CH(3)COOH. We found that 3 reacts with 1,3-bis (2,4,6-trimethylphenyl)-1,3-dihydro...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8787765/ https://www.ncbi.nlm.nih.gov/pubmed/34989739 http://dx.doi.org/10.1039/d1dt03966k |