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Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

Chlorobenzenes are important starting materials for the preparation of commercially valuable triarylphosphines and tetraarylphosphonium salts, but their use for the direct arylation of elemental phosphorus has been elusive. Here we describe a simple photochemical route toward such products. UV-LED i...

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Detalles Bibliográficos
Autores principales: Till, Marion, Streitferdt, Verena, Scott, Daniel J., Mende, Michael, Gschwind, Ruth M., Wolf, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8788315/
https://www.ncbi.nlm.nih.gov/pubmed/34889916
http://dx.doi.org/10.1039/d1cc05691c