What Singles out Aluminyl Anions? A Comparative Computational Study of the Carbon Dioxide Insertion Reaction in Gold–Aluminyl, −Gallyl, and −Indyl Complexes

[Image: see text] Anionic aluminum(I) anions (“aluminyls”) are the most recent discovery along Group 13 anions, and the understanding of the unconventional reactivity they are able to induce at a coordinated metal site is at an early stage. A striking example is the efficient insertion of carbon dio...

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Detalles Bibliográficos
Autores principales: Sorbelli, Diego, Belpassi, Leonardo, Belanzoni, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790757/
https://www.ncbi.nlm.nih.gov/pubmed/34986633
http://dx.doi.org/10.1021/acs.inorgchem.1c03579

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790757/
https://www.ncbi.nlm.nih.gov/pubmed/34986633
http://dx.doi.org/10.1021/acs.inorgchem.1c03579

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