Divergent stereochemical outcomes in the insertion of donor/donor carbenes into the C–H bonds of stereogenic centers

Intramolecular C–H insertions with donor/donor dirhodium carbenes provide a concise and highly stereoselective method to set two contiguous stereocenters in a single step. Herein, we report the insertion of donor/donor carbenes into stereogenic carbon centers allowing access to trisubstituted benzod...

Descripción completa

Detalles Bibliográficos
Autores principales: Dishman, Sarah N., Laconsay, Croix J., Fettinger, James C., Tantillo, Dean J., Shaw, Jared T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790770/
https://www.ncbi.nlm.nih.gov/pubmed/35211269
http://dx.doi.org/10.1039/d1sc04622e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790770/
https://www.ncbi.nlm.nih.gov/pubmed/35211269
http://dx.doi.org/10.1039/d1sc04622e

Ejemplares similares