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Metal-free, visible-light induced enantioselective three-component dicarbofunctionalization and oxytrifluoromethylation of enamines via chiral phosphoric acid catalysis

Using diverse carbon-centered radical precursors and electron-rich (hetero)aromatics and alcohols as nucleophiles, a visible-light driven chiral phosphoric acid (CPA) catalyzed asymmetric intermolecular, three-component radical-initiated dicarbofunctionalization and oxytrifluoromethylation of enamin...

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Detalles Bibliográficos
Autores principales: Liang, Hui, Ji, Dong-Sheng, Xu, Guo-Qiang, Luo, Yong-Chun, Zheng, Haixue, Xu, Peng-Fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790774/
https://www.ncbi.nlm.nih.gov/pubmed/35211274
http://dx.doi.org/10.1039/d1sc06613g