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Unveiling a key catalytic pocket for the ruthenium NHC-catalysed asymmetric heteroarene hydrogenation

The chiral ruthenium(ii)bis-SINpEt complex is a versatile and powerful catalyst for the hydrogenation of a broad range of heteroarenes. This study aims to provide understanding of the active form of this privileged catalyst as well as the reaction mechanism, and to identify the factors which control...

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Detalles Bibliográficos
Autores principales: Hamza, Andrea, Moock, Daniel, Schlepphorst, Christoph, Schneidewind, Jacob, Baumann, Wolfgang, Glorius, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790799/
https://www.ncbi.nlm.nih.gov/pubmed/35211263
http://dx.doi.org/10.1039/d1sc06409f