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Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations

Bi(2)S(3) was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl(3) (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi(7)S(8))[S(AlCl(3))(3)](2)[AlCl(4)](2) (1) precipitated. X‐ra...

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Detalles Bibliográficos
Autores principales: Knies, Maximilian, Ruck, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8805384/
https://www.ncbi.nlm.nih.gov/pubmed/34390229
http://dx.doi.org/10.1002/open.202100145