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Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations
Bi(2)S(3) was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl(3) (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi(7)S(8))[S(AlCl(3))(3)](2)[AlCl(4)](2) (1) precipitated. X‐ra...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8805384/ https://www.ncbi.nlm.nih.gov/pubmed/34390229 http://dx.doi.org/10.1002/open.202100145 |
| _version_ | 1784643240248475648 |
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| author | Knies, Maximilian Ruck, Michael |
| author_facet | Knies, Maximilian Ruck, Michael |
| author_sort | Knies, Maximilian |
| collection | PubMed |
| description | Bi(2)S(3) was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl(3) (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi(7)S(8))[S(AlCl(3))(3)](2)[AlCl(4)](2) (1) precipitated. X‐ray diffraction on single‐crystals of 1 revealed a triclinic crystal structure that contains (Bi(7)S(8))(5+) spiro‐dicubanes, [S(AlCl(3))(3)](2−) tetrahedra triples, isolated [AlCl(4)](−) tetrahedra, and sodium cations. |
| format | Online Article Text |
| id | pubmed-8805384 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-88053842022-02-04 Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations Knies, Maximilian Ruck, Michael ChemistryOpen Full Papers Bi(2)S(3) was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl(3) (BMIm=1‐n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of Na(Bi(7)S(8))[S(AlCl(3))(3)](2)[AlCl(4)](2) (1) precipitated. X‐ray diffraction on single‐crystals of 1 revealed a triclinic crystal structure that contains (Bi(7)S(8))(5+) spiro‐dicubanes, [S(AlCl(3))(3)](2−) tetrahedra triples, isolated [AlCl(4)](−) tetrahedra, and sodium cations. John Wiley and Sons Inc. 2021-08-13 /pmc/articles/PMC8805384/ /pubmed/34390229 http://dx.doi.org/10.1002/open.202100145 Text en © 2021 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| spellingShingle | Full Papers Knies, Maximilian Ruck, Michael Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_full | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_fullStr | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_full_unstemmed | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_short | Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations |
| title_sort | ionothermal synthesis of sulfidobismuth spiro‐dicubane cations |
| topic | Full Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8805384/ https://www.ncbi.nlm.nih.gov/pubmed/34390229 http://dx.doi.org/10.1002/open.202100145 |
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