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HERFD-XANES and RIXS Study on the Electronic Structure of Trivalent Lanthanides across a Series of Isostructural Compounds

[Image: see text] We performed a systematic study of the complexes of trivalent lanthanide cations with the hydridotris(1-pyrazolyl)borato (Tp) ligand (LnTp(3); Ln = La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, and Lu) using both high-energy-resolution fluorescence-detected X-ray absorption near-...

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Detalles Bibliográficos
Autores principales: Zasimov, Pavel, Amidani, Lucia, Retegan, Marius, Walter, Olaf, Caciuffo, Roberto, Kvashnina, Kristina O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8808409/
https://www.ncbi.nlm.nih.gov/pubmed/35051333
http://dx.doi.org/10.1021/acs.inorgchem.1c01525