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C(sp(3))–H oxygenation via alkoxypalladium(ii) species: an update for the mechanism

Pd-catalyzed C(sp(3))–H oxygenation has emerged as an attractive strategy for organic synthesis. The most commonly proposed mechanism involves C(sp(3))–H activation followed by oxidative addition of an oxygen electrophile to give an alkylpalladium(iv) species and further C(sp(3))–O reductive elimina...

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Detalles Bibliográficos
Autores principales: Zhang, Shuaizhong, Zhang, Jinquan, Zou, Hongbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8809414/
https://www.ncbi.nlm.nih.gov/pubmed/35222913
http://dx.doi.org/10.1039/d1sc06907a