Cargando…

C(sp(3))–H oxygenation via alkoxypalladium(ii) species: an update for the mechanism

Pd-catalyzed C(sp(3))–H oxygenation has emerged as an attractive strategy for organic synthesis. The most commonly proposed mechanism involves C(sp(3))–H activation followed by oxidative addition of an oxygen electrophile to give an alkylpalladium(iv) species and further C(sp(3))–O reductive elimina...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zhang, Shuaizhong, Zhang, Jinquan, Zou, Hongbin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8809414/ https://www.ncbi.nlm.nih.gov/pubmed/35222913 http://dx.doi.org/10.1039/d1sc06907a

Ejemplares similares

Temperature-modulated selective C(sp(3))–H or C(sp(2))–H arylation through palladium catalysis
por: Gogula, Thirupathi, et al.
Publicado: (2020)

Transition-metal-free C(sp(3))–H/C(sp(3))–H dehydrogenative coupling of saturated heterocycles with N-benzyl imines
por: Liu, Zhengfen, et al.
Publicado: (2020)

Copper(ii) ketimides in sp(3) C–H amination
por: Jayasooriya, Isuri U., et al.
Publicado: (2021)

Room temperature C(sp(2))–H oxidative chlorination via photoredox catalysis
por: Zhang, Lei, et al.
Publicado: (2017)

Intramolecular 1,5-C(sp(3))–H radical amination via Co(ii)-based metalloradical catalysis for five-membered cyclic sulfamides
por: Lu, Hongjian, et al.
Publicado: (2016)

An iron(ii)-based metalloradical system for intramolecular amination of C(sp(2))–H and C(sp(3))–H bonds: synthetic applications and mechanistic studies
por: Das, Sandip Kumar, et al.
Publicado: (2022)

Nickel(ii)-catalyzed tandem C(sp(2))–H bond activation and annulation of arenes with gem-dibromoalkenes
por: Shi, Yun, et al.
Publicado: (2018)

Versatile telluracycle synthesis via the sequential electrophilic telluration of C(sp(2))–Zn and C(sp(2))–H bonds
por: Wu, Bin, et al.
Publicado: (2017)

sp(3) C–H activation via exo-type directing groups
por: Xu, Yan, et al.
Publicado: (2018)

Chemo- and regioselective oxygenation of C(sp(3))–H bonds in aliphatic alcohols using a covalently bound directing activator and atmospheric oxygen
por: Ozawa, Jun, et al.
Publicado: (2016)

Electrochemical C–H oxygenation and alcohol dehydrogenation involving Fe-oxo species using water as the oxygen source
por: Das, Amit, et al.
Publicado: (2019)

Pd(ii)-catalyzed β- and γ-C-(sp(3))–H dienylation with allenyl acetates
por: Shukla, Rahul K., et al.
Publicado: (2022)

Pd-catalyzed cross-electrophile Coupling/C–H alkylation reaction enabled by a mediator generated via C(sp(3))–H activation
por: Wu, Zhuo, et al.
Publicado: (2021)

Mechanism of the Cu(II)-catalyzed benzylic oxygenation of (aryl)(heteroaryl)methanes with oxygen
por: Sterckx, Hans, et al.
Publicado: (2016)

Stoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C(sp(2))–H arylation
por: Wu, Qian, et al.
Publicado: (2015)

Copper-catalyzed diastereoselective aerobic intramolecular dehydrogenative coupling of hydrazones via sp(3) C–H functionalization
por: Wu, Xuesong, et al.
Publicado: (2015)

Mechanisms of Reactive Oxygen Species Generated by Inorganic Nanomaterials for Cancer Therapeutics
por: Zhang, Lizhen, et al.
Publicado: (2021)

Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp(3))–H borylation of chlorosilanes
por: Huang, Genping, et al.
Publicado: (2015)

Cobalt-catalyzed C(sp(3))–H/C(sp(2))–H oxidative coupling between alkanes and benzamides
por: Li, Shuangjie, et al.
Publicado: (2018)

Site-selective carbonylation of arenes via C(sp(2))–H thianthrenation: direct access to 1,2-diarylethanones
por: Zhang, Jiajun, et al.
Publicado: (2023)

Metal-free C(sp(3))–H functionalization of sulfonamides via strain-release rearrangement
por: Hu, Jiefeng, et al.
Publicado: (2021)

Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
por: Huang, Chia-Yu, et al.
Publicado: (2022)

A diversity-oriented synthesis of bioactive benzanilides via a regioselective C(sp(2))–H hydroxylation strategy
por: Sun, Yong-Hui, et al.
Publicado: (2016)

Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))–H bond functionalisation
por: Czyz, Milena L., et al.
Publicado: (2020)

A multi pathway coupled domino strategy: I(2)/TBHP-promoted synthesis of imidazopyridines and thiazoles via sp(3), sp(2) and sp C–H functionalization
por: Wang, Yishou, et al.
Publicado: (2022)

The site-selectivity and mechanism of Pd-catalyzed C(sp(2))–H arylation of simple arenes
por: Kim, Daeun, et al.
Publicado: (2020)

Metal-free visible-induced C(sp(2))–C(sp(2)) coupling of quinoxalin-2(H)-ones via oxidative cleavage of the C–N bond
por: Wu, Mei, et al.
Publicado: (2023)

Sarcosenones A–C, highly oxygenated pimarane diterpenoids from an endolichenic fungus Sarcosomataceae sp.
por: Hou, Xintong, et al.
Publicado: (2020)

Copper-catalyzed oxidative C(sp(3))–H/C(sp(2))–H cross-coupling en route to carbocyclic rings
por: Wang, Rui, et al.
Publicado: (2017)

Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp(2))–H and unactivated C(sp(3))–H bonds
por: Wu, Xuesong, et al.
Publicado: (2015)

Modular synthesis of dihydro-isoquinolines: palladium-catalyzed sequential C(sp(2))–H and C(sp(3))–H bond activation
por: Liu, Weidong, et al.
Publicado: (2015)

Ni(0)-promoted activation of C(sp(2))–H and C(sp(2))–O bonds
por: Min, Sehye, et al.
Publicado: (2021)

Late-stage C(sp(2))–H and C(sp(3))–H glycosylation of C-aryl/alkyl glycopeptides: mechanistic insights and fluorescence labeling
por: Wu, Jun, et al.
Publicado: (2020)

A photoinduced transient activating strategy for late-stage chemoselective C(sp(3))–H trifluoromethylation of azines
por: Huang, Mengjun, et al.
Publicado: (2022)

Advances in the site-selective C-5, C-3 and C-2 functionalization of chromones via sp(2) C–H activation
por: Benny, Anjitha Theres, et al.
Publicado: (2022)

Diverse secondary C(sp(3))–H bond functionalization via site-selective trifluoroacetoxylation of aliphatic amines
por: Tang, Yongzhen, et al.
Publicado: (2018)

Practical, metal-free remote heteroarylation of amides via unactivated C(sp(3))–H bond functionalization
por: Tang, Nana, et al.
Publicado: (2019)

Allylic C(sp(3))–H alkylation via synergistic organo- and photoredox catalyzed radical addition to imines
por: Jia, Jiaqi, et al.
Publicado: (2020)

Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of γ-C(sp(3))–H bonds of aliphatic amine substrates
por: Wang, Chao, et al.
Publicado: (2015)

Role of mutations in a chemoenzymatic enantiodivergent C(sp(3))–H insertion: exploring the mechanism and origin of stereoselectivity
por: Chatterjee, Ritwika, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_3iglfbh8s8ktb68939nghbt391