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Diverse saturated heterocycles from a hydroacylation/conjugate addition cascade
Rhodium-catalyzed hydroacylation using alkynes substituted with pendant nucleophiles, delivers linear α,β-unsaturated enone intermediates with excellent regioselectivity. These adducts are used to construct a broad range of diversely substituted, saturated O-, N- and S-heterocycles in a one-pot proc...
Autores principales: | Iwumene, Ndidi U. N., Moseley, Daniel. F., Pullin, Robert D. C., Willis, Michael C. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8809418/ https://www.ncbi.nlm.nih.gov/pubmed/35222935 http://dx.doi.org/10.1039/d1sc06900d |
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