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Luminescent cis-Bis(bipyridyl)ruthenium(II) Complexes with 1,2-Azolylamidino Ligands: Photophysical, Electrochemical Studies, and Photocatalytic Oxidation of Thioethers

[Image: see text] New 1,2-azolylamidino complexes cis-[Ru(bipy)(2)(NH=C(R)az*-κ(2)N,N)](OTf)(2) (R = Me, Ph; az* = pz, indz, dmpz) are synthesized via chloride abstraction after a subsequent base-catalyzed coupling of a nitrile with the previously coordinated 1,2-azole. The synthetic procedure allow...

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Detalles Bibliográficos
Autores principales: Cuéllar, Elena, Diez-Varga, Alberto, Torroba, Tomás, Domingo-Legarda, Pablo, Alemán, José, Cabrera, Silvia, Martín-Alvarez, Jose M., Miguel, Daniel, Villafañe, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8812113/
https://www.ncbi.nlm.nih.gov/pubmed/33905238
http://dx.doi.org/10.1021/acs.inorgchem.0c03389