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Switching Hydrogen Bonding to π-Stacking: The Thiophenol Dimer and Trimer
[Image: see text] We used jet-cooled broadband rotational spectroscopy to explore the balance between π-stacking and hydrogen-bonding interactions in the self-aggregation of thiophenol. Two different isomers were detected for the thiophenol dimer, revealing dispersion-controlled π-stacked structures...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8812119/ https://www.ncbi.nlm.nih.gov/pubmed/33507084 http://dx.doi.org/10.1021/acs.jpclett.0c03797 |