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Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]
The reaction of Ag[C(5)(CN)(5)] with anhydrous FeCl(2) in acetonitrile leads to colourless crystals of tetrakis(acetonitrile-κN)bis(pentacyanocyclopentadienido-κN)iron(II) acetonitrile 1.8-solvate, [Fe(C(10)N(5))(2)(CH(3)CN)(4)]·1.8CH(3)CN or cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]·1.8MeCN. The...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8815677/ https://www.ncbi.nlm.nih.gov/pubmed/35119387 http://dx.doi.org/10.1107/S2053229622000365 |