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Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]
The reaction of Ag[C(5)(CN)(5)] with anhydrous FeCl(2) in acetonitrile leads to colourless crystals of tetrakis(acetonitrile-κN)bis(pentacyanocyclopentadienido-κN)iron(II) acetonitrile 1.8-solvate, [Fe(C(10)N(5))(2)(CH(3)CN)(4)]·1.8CH(3)CN or cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]·1.8MeCN. The...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8815677/ https://www.ncbi.nlm.nih.gov/pubmed/35119387 http://dx.doi.org/10.1107/S2053229622000365 |
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| author | Sünkel, Karlheinz Blockhaus, Tobias |
| author_facet | Sünkel, Karlheinz Blockhaus, Tobias |
| author_sort | Sünkel, Karlheinz |
| collection | PubMed |
| description | The reaction of Ag[C(5)(CN)(5)] with anhydrous FeCl(2) in acetonitrile leads to colourless crystals of tetrakis(acetonitrile-κN)bis(pentacyanocyclopentadienido-κN)iron(II) acetonitrile 1.8-solvate, [Fe(C(10)N(5))(2)(CH(3)CN)(4)]·1.8CH(3)CN or cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]·1.8MeCN. The compound crystallizes in the triclinic space group P [Image: see text] as monomers, which exhibit weak C—H⋯N and π–π interactions. The crystals contain ca 20% solvent-accessible voids, which are nearly completely filled by two MeCN molecules. |
| format | Online Article Text |
| id | pubmed-8815677 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-88156772022-02-09 Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe] Sünkel, Karlheinz Blockhaus, Tobias Acta Crystallogr C Struct Chem Research Papers The reaction of Ag[C(5)(CN)(5)] with anhydrous FeCl(2) in acetonitrile leads to colourless crystals of tetrakis(acetonitrile-κN)bis(pentacyanocyclopentadienido-κN)iron(II) acetonitrile 1.8-solvate, [Fe(C(10)N(5))(2)(CH(3)CN)(4)]·1.8CH(3)CN or cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]·1.8MeCN. The compound crystallizes in the triclinic space group P [Image: see text] as monomers, which exhibit weak C—H⋯N and π–π interactions. The crystals contain ca 20% solvent-accessible voids, which are nearly completely filled by two MeCN molecules. International Union of Crystallography 2022-01-21 /pmc/articles/PMC8815677/ /pubmed/35119387 http://dx.doi.org/10.1107/S2053229622000365 Text en © Sünkel and Blockhaus 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Papers Sünkel, Karlheinz Blockhaus, Tobias Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe] |
| title | Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe] |
| title_full | Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe] |
| title_fullStr | Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe] |
| title_full_unstemmed | Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe] |
| title_short | Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe] |
| title_sort | coordination chemistry of polynitriles. part 9. decacyanoferrocene revisited: crystal and molecular structure of cis-[{c(5)(cn)(5)}(2)(mecn)(4)fe] |
| topic | Research Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8815677/ https://www.ncbi.nlm.nih.gov/pubmed/35119387 http://dx.doi.org/10.1107/S2053229622000365 |
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